徐允河

2026

Mg‐Mediated Dual Cross‐Electrophile Coupling of Propargyl and Allyl Dichlorides with Chlorosilanes: Access to Disilyl‐substituted Allene and Bis(Silyl)Propenes

Angewandte Chemie

DOI

2026

Stereoselective Construction and Skeletal Reorganization of Conjugated Enynes

Organic Letters

DOI

2025

Enantioselective Synthesis of Disilacyclohexenes via Nickel-Catalyzed Asymmetric Reductive [4 + 2] Sila-Cycloaddition

ACS Catalysis

DOI

2025

Ligand-Controlled Regiodivergent Hydrosilylation of α,β-Unsaturated Esters

ACS Catalysis

DOI

2025

Copper-Catalyzed Regio- and Enantioselective Hydrosilylation of Internal Alkynes for Synthesis of Si-Stereogenic Vinylsilanes

ACS Catalysis

DOI

2025

Cobalt-Catalyzed Regioselective Intramolecular Hydrosilylation of Olefins to Access Sila-heterocycles

Organic Letters

DOI

2025

Palladium-Catalyzed Regio- and Stereoselective C–H Alkynylation of Conjugated Dienols

JACS Au

DOI

2025

Modular construction of α- or β-stereogenic organosilanes and organogermanes via enantioselective alkene hydroalkylation

Nature Synthesis

DOI

2025

Copper-catalyzed intermolecular Regio- and Enantioselective Hydrosilylation of Alkenes with Prochiral Silanes

Nature Communications

DOI

2025

Copper-catalyzed stereo-controllable silylation of allylic gem -dichlorides

Organic Chemistry Frontiers

DOI

2024

Palladium-catalyzed desymmetric coupling reaction between silacyclobutanes and terminal alkynes for the synthesis of silicon-stereogenic allyl vinylsilanes

Tetrahedron Chem

DOI

2024

Cu-Catalyzed Regioselective Silylation of Chloro-Substituted Allenyl-Bdan

Organic Letters

DOI

2024

Regiodivergent Hydrosilylation of Polar Enynes to Synthesize Site‐Specific Silyl‐Substituted Dienes

Angewandte Chemie

DOI

2024

Progress in the Synthesis of Cyclobutenones

European Journal of Organic Chemistry

DOI

2024

Copper-catalyzed S-vinylation of sulfenamides for the synthesis of α,β-unsaturated sulfilimines

Cell Reports Physical Science

DOI

2024

Copper‐Catalyzed Ring‐Opening Hydrosilylation and Hydroboration of Arylidenecyclopropanes

Chinese Journal of Chemistry

DOI

2024

Copper‐Catalyzed Alkenylation and Alkenyloxylation with‐Alkenyl(phenyl)iodonium Salts

Advanced Synthesis & Catalysis

DOI

2024

Enantioselective construction of Si-stereogenic linear alkenylhydrosilanes via copper-catalyzed hydrosilylation of alkynes

Chem Catalysis

DOI

2023

铜催化双炔膦氧化物硅质子化反应合成β-硅基取代的乙烯基膦氧化物（英文）

《有机化学》

2023

Synthesis and Transformation of Bis(silyl)-Substituted Conjugated Vinylallene Compounds

Organic Letters

DOI

2023

Copper-Catalyzed Enantioselective Desymmetric Protosilylation of Prochiral Diynes: Access to Optically Functionalized Tertiary Alcohols

Organic Letters

DOI

2023

Copper-Catalyzed Regio- and Stereoselective Three-Component Coupling of Allenyl Ethers with gem-Dichlorocyclobutenones and B2pin2

Organic Letters

DOI

2023

Copper-Catalyzed Borylation and Silylation of Dichlorocyclobutenones

Organic Letters

DOI

2023

Regioselective Synthesis of β-Silyl-Substituted Vinylphosphine Oxides via Copper-Catalyzed Protosilylation of Dialkynylphosphine Oxides

Chinese Journal of Organic Chemistry

DOI

2023

Highly regio- and stereoselective bromochlorination and bromoazidation of 1,3-dienes

Organic Chemistry Frontiers

DOI

2023

Copper-catalyzed desymmetric silylative-cyclization of 1,6-diynes for synthesis of spirocyclic compounds

Organic Chemistry Frontiers

DOI

2023

Progress on the Enantioselective Synthesis of Axially Chiral Cycloalkylidenes

Synthesis

DOI

2023

Regio- and enantioselective CuH-catalyzed 1,2- and 1,4-hydrosilylation of 1,3-enynes

Nature Communications

DOI

2023

Copper-catalyzed 1,4-protosilylation and 1,4-protoborylation of enynic orthoesters for synthesis of functionalized 2,3-allenoates

Chinese Chemical Letters

DOI

2022

铜催化1,4-二炔硼质子化反应制备支链烯基硼化合物（英文）

Journal of University of Science and Technology of China

2022

Copper-Catalyzed Enantioselective Hydrosilylation of Allenes to Access Axially Chiral (Cyclohexylidene)ethyl Silanes

Organic Letters

DOI

2022

Copper-Catalyzed Markovnikov Selective 3,4-Hydrosilylation of 2-Substituted 1,3-Dienes

Organic Letters

DOI

2022

Copper-Catalyzed Enantioselective 1,4-Protosilylation of Alkynyl-substituted Enones to Synthesize the Highly Diastereomeric Chiral Homoallenylsilanes

Organic Letters

DOI

2022

Synthesis of Allenyl-Bdan via Cu(I)-Catalyzed Borylation of Propargyl gem-Dichlorides

Organic Letters

DOI

2022

Chelation-Controlled Stereospecific Cross-Coupling Reaction between Alkenes for Atroposelective Synthesis of Axially Chiral Conjugated Dienes

Organic Letters

DOI

2022

Transition Metal‐Catalyzed Oxidative Cross‐Coupling Between Olefins

Handbook of CH‐Functionalization

DOI

2022

Copper-Catalyzed Regiodivergent and Enantioselective Hydrosilylation of Allenes

Journal of the American Chemical Society

DOI

2022

Synthesis and Application of β‐Alkynyl‐γ,γ‐Difluoroallylboronates for Metal‐Free Allylation of Aldehydes in Water

Advanced Synthesis & Catalysis

DOI

2022

Dienylation of N -benzoylhydrazones with CF 3 -substituted homoallenylboronates in water

Organic & Biomolecular Chemistry

DOI

2021

钯催化串联Heck环化反应制备氮杂桥环化合物（英文）

《有机化学》

2021

铜催化共轭乙烯基联烯硅和1,3-二烯硅合成

Journal of Molecular Science

DOI

2021

Palladium-Catalyzed Tandem Heck Cyclization Reactions to Access the Bridged N-Heterocyclic Compounds

Youji huaxue

DOI

2021

Asymmetric Synthesis of Chiral Allenes

Axially Chiral Compounds

DOI

2021

Synthesis of Structurally Diverse Allylsilanes via Copper-Catalyzed Regiodivergent Hydrosilylation of 1,3-Dienes

Organic Letters

DOI

2021

Copper-Catalyzed Chemoselective Silylative Cyclization of 2,2′-Diethynylbiaryl Derivatives

Organic Letters

DOI

2021

Copper Catalyzed Protosilylation/Protoborylation of gem‐Difluoroallenes

European Journal of Organic Chemistry

DOI

2021

Synthesis of Enynic and Allenic Orthoesters via Defluoromethoxylation of 2-Trifluoromethyl-1,3-enynes

Organic Letters

DOI

2021

Controllable regio- and stereo-selective coupling reactions of homoallenylboronates

Organic Chemistry Frontiers

DOI

2020

Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes

Organic Letters

DOI

2020

Catalytic Asymmetric Conjugate Protosilylation and Protoborylation of 2-Trifluoromethyl Enynes for Synthesis of Functionalized Allenes

Organic Letters

DOI

2020

Synthesis of Functionalized Vinylsilanes via Metal-Free Dehydrogenative Silylation of Enamides

Organic Letters

DOI

2019

Copper‐Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes

Angewandte Chemie

DOI

2019

Palladium-Catalyzed Cycloaromatization/Alkylation of o-(Alkynyl)styrenes

The Journal of Organic Chemistry

DOI

2019

Ligand-Dependent-Controlled Copper-Catalyzed Regio- and Stereoselective Silaboration of Alkynes

Organic Letters

DOI

2019

Palladium-Catalyzed Cascade Intramolecular Cyclization and Allylation of Enynoates with Allylic Alcohols

The Journal of Organic Chemistry

DOI

2019

Palladium-Catalyzed Dialkylation of C–C Triple Bonds: Access to Multi-Functionalized Indenes

Organic Letters

DOI

2019

Divergent Protosilylation and Protoborylation of Polar Enynes

Organic Letters

DOI

2019

Palladium(II)-Catalyzed Stereospecific Alkenyl C–H Bond Alkylation of Allylamines with Alkyl Iodides

ACS Catalysis

DOI

2019

Copper-catalyzed regiodivergent 1,4- and 1,6-conjugate silyl addition to diendioates: access to functionalized allylsilanes

Organic & Biomolecular Chemistry

DOI

2018

Palladium-Catalyzed One-Pot Highly Regioselective 6-Endo Cyclization and Alkylation of Enynoates: Synthesis of 2-Alkanone Pyrones

The Journal of Organic Chemistry

DOI

2018

Palladium-Catalyzed Regioselective Olefination of O-Acetyl Cyanohydrins

The Journal of Organic Chemistry

DOI

2018

Copper-Catalyzed Dehydrogenative Diels–Alder Reaction

Organic Letters

DOI

2018

Copper-Catalyzed Stereo- and Enantioselective 1,4-Protosilylation of α,β-Unsaturated Ketimines To Synthesize Functionalized Allylsilanes

ACS Catalysis

DOI

2018

Catalytically Asymmetric Synthesis of 1,3-Bis(silyl)propenes via Copper-Catalyzed Double Proto-Silylations of Polar Enynes

ACS Catalysis

DOI

2018

Palladium-catalyzed silaborative carbocyclizations of 1,6-diynes

Chemical Communications

DOI

2018

Multi-catalyst promoted asymmetric relay reactions

Organic Chemistry Frontiers

DOI

2017

Macrolide Synthesis through Intramolecular Oxidative Cross‐Coupling of Alkenes

Angewandte Chemie

DOI

2017

Copper-Catalyzed Silylperoxidation Reaction of α,β-Unsaturated Ketones, Esters, Amides, and Conjugated Enynes

ACS Catalysis

DOI

2017

Chelation versus Non‐Chelation Control in the Stereoselective Alkenyl sp2 C−H Bond Functionalization Reaction

Angewandte Chemie

DOI

2017

Palladium-Catalyzed Direct Intramolecular C–N Bond Formation: Access to Multisubstituted Dihydropyrroles

Organic Letters

DOI

2017

Copper-catalyzed silylation reactions of propargyl epoxides: easy access to 2,3-allenols and stereodefined alkenes

Chemical Communications

DOI

2017

An iron-catalyzed hydroalkylation reaction of α,β-unsaturated ketones with ethers

Chemical Communications

DOI

2017

Direct coupling of sp 3 carbon of alkanes with α,β-unsaturated carbonyl compounds using a copper/hydroperoxide system

Organic Chemistry Frontiers

DOI

2016

Anomalous Reactivity and Selectivity in the Intermolecular Diels–Alder Reactions of Multisubstituted Acyclic Dienes with Geometrical Isomers of Enals

Organic Letters

DOI

2016

Palladium-catalyzed cross-coupling of enamides with sterically hindered α-bromocarbonyls

Chemical Communications

DOI

2016

Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Chemical Communications

DOI

2016

Stereoselective Synthesis of cis‐2,5‐Disubstituted Pyrrolidines via Copper‐Catalyzed Cyclization of Alkenes

Chinese Journal of Chemistry

DOI

2015

B(C6F5)3: A New Class of Strong and Bulky Lewis Acid for Exo-Selective Intermolecular Diels–Alder Reactions of Unreactive Acyclic Dienes with α,β-Enals

Organic Letters

DOI

2015

Selective Dealkylation of Alkyl Aryl Ethers

Asian Journal of Organic Chemistry

DOI

2015

Palladium-Catalyzed Intermolecular Oxyarylation of Vinylacetates with Retention of an Alkenyl Moiety

Organic Letters

DOI

2015

Highly Enantioselective and Anti-Diastereoselective Catalytic Intermolecular Glyoxylate–Ene Reactions: Effect of the Geometrical Isomers of Alkenes

Organic Letters

DOI

2015

Palladium-Catalyzed Difunctionalization of Internal Alkynes via Highly Regioselective 6-Endo Cyclization and Alkenylation of Enynoates: Synthesis of Multisubstituted Pyrones

Organic Letters

DOI

2015

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

Journal of the American Chemical Society

DOI

2015

Copper‐Catalyzed Enantioselective Conjugate Addition of Grignard Reagents to Methyl 4,4,4‐Trifluorocrotonate: Synthesis of Enantioenriched Trifluoromethylated Compounds

Chemistry - An Asian Journal

DOI

2015

Stereo- and Chemoselective Cross-Coupling between Two Electron-Deficient Acrylates: An Efficient Route to ( Z , E )-Muconate Derivatives

Journal of the American Chemical Society

DOI

2014

Mild Rh(III)-Catalyzed Direct C–H Bond Arylation of (Hetero)Arenes with Arylsilanes in Aqueous Media

Organic Letters

DOI

2014

Synthesis of multi-substituted pyrroles using enamides and alkynes catalyzed by Pd(OAc) 2 with molecular oxygen as an oxidant

Chemical Communications

DOI

2014

Preparation of highly substituted (β-acylamino)acrylates via iron-catalyzed alkoxycarbonylation of N-vinylacetamides with carbazates

Chemical Communications

DOI

2014

Synthesis of multi-substituted vinylsilanes via copper( i )-catalyzed hydrosilylation reactions of allenes and propiolate derivatives with silylboronates

Chemical Communications

DOI

2014

Pd-Catalyzed Intramolecular C–N Bond Cleavage, 1,4-Migration, sp 3 C–H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand

Journal of the American Chemical Society

DOI

2014

Palladium‐Catalyzed Direct Alkynylation of N‐Vinylacetamides

Advanced Synthesis & Catalysis

DOI

2013

仿生阳离子多烯环化

《中国科学技术大学学报》

2013

Synthesis of Dienyl Ketones via Palladium(II)-Catalyzed Direct Cross-Coupling Reactions between Simple Alkenes and Vinyl Ketones: Application to the Synthesis of Vitamin A1 and Bornelone

Organic Letters

DOI

2013

Palladium-catalyzed alkenyl C–H bond sulfonylation reaction using organosulfonyl chlorides

Tetrahedron

DOI

2013

ChemInform Abstract: Palladium‐Catalyzed Alkenyl C—H Bond Sulfonylation Reaction Using Organosulfonyl Chlorides.

ChemInform

DOI

2013

Palladium(ii)-catalyzed cross-coupling of simple alkenes with acrylates: a direct approach to 1,3-dienes through C–H activation

Chemical Science

DOI

2012

Palladium‐Catalyzed Direct CH Arylation of Enamides with Simple Arenes

Angewandte Chemie

DOI

2012

Organoindium Reagents: The Preparation and Application in Organic Synthesis

Chemical Reviews

DOI

2012

Palladium‐Catalyzed Cross‐Coupling of Unactivated Alkenes with Acrylates: Application to the Synthesis of the C13–C21 Fragment of Palmerolide A

Chemistry - A European Journal

DOI

2011

Palladium(II)-catalyzed alkenyl c-h bond functionalization.

DOI

2007

Synthesis, Crystal Structure and Spectral Properties of [Fe3(2,2′-bipy)6(ox)3]·12.25H2O Complex

DOI