卓庆德｜中国科学技术大学｜学者主页

2026

Cascade Coupling of Dinitrogen, Carbon Monoxide, Carbon Dioxide, and Alkynes in a Dititanium Framework.

Xiaoxi Zhou, Qingde Zhuo, Lei Shi, T. Shima, Meng-Yang Li, Gen Luo, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2026

Dinitrogen Functionalization with Allene, Isocyanide, and Carbon Monoxide in a Dititanium Framework.

Xiaoxi Zhou, Qingde Zhuo, Tong Liu, T. Shima, Meng-Yang Li, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2025

Construction of Multiple M–C Bonds: Chelation with Conjugated Carbon Chains

Xiaoxi Zhou, Qingde Zhuo

Chinese Journal of Chemistry

DOI

2025

A ruthenium carbolong skeleton with ten carbon atoms

Jiaomei Guo, Zhengyu Lü, Wenhao Zhou, Qingde Zhuo, Dafa Chen, Haiping Xia

Inorganic Chemistry Frontiers

DOI

2025

Denitrogenative Carbon Skeleton Cleavage and Reorganization of Pyridines by a Trinuclear Titanium Polyhydride Complex.

Xiaoxi Zhou, Shaowei Hu, Qingde Zhuo, Gen Luo, T. Shima, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2025

Enantioselective [3+2] Annulation of Aldimines with Alkynes by Scandium-Catalyzed C-H Activation.

A. Mishra, Jiameng Hu, Xue-Feng Cong, Qingde Zhuo, M. Nishiura, Gen Luo, Zhao-Min Hou

Angewandte Chemie

DOI

2025

Regio- and Stereoselective Hydroalkynylation of Internal Alkynes with Terminal Alkynes by Half-Sandwich Rare-Earth Catalysts.

Na Hao, Teng-Gang Jiao, Zhou Sun, A. Mishra, Qingde Zhuo, M. Nishiura, Zhao-Min Hou, Xue-Feng Cong

Journal of the American Chemical Society

DOI

2024

Dinitrogen Cleavage and Multicoupling with Isocyanides in a Dititanium Dihydride Framework.

Qingde Zhuo, Jimin Yang, Xiaoxi Zhou, T. Shima, Yi Luo, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2024

Denitrogenative Ring-Contraction of Pyridines to a Cyclopentadienyl Skeleton at a Dititanium Hydride Framework.

Xiaoxi Zhou, Qingde Zhuo, T. Shima, Xiao-nan Kang, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2024

Regio- and Diastereoselective Annulation of α,β-Unsaturated Aldimines with Alkenes via Allylic C(sp3)-H Activation by Rare-Earth Catalysts.

Xue-Feng Cong, Na Hao, A. Mishra, Qingde Zhuo, Kun An, M. Nishiura, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2024

Divergent Synthesis of Multi-Substituted Aminotetralins via [4+2] Annulation of Aldimines with Alkenes by Rare-Earth-Catalyzed Benzylic C(sp3)-H Activation.

Xue-Feng Cong, Qingde Zhuo, Na Hao, A. Mishra, M. Nishiura, Zhao-Min Hou

Angewandte Chemie

DOI

2024

(Z)-Selective Isomerization of 1,1-Disubstituted Alkenes by Scandium-Catalyzed Allylic C-H Activation.

Shaojie Lou, Pan Wang, Xin Wen, A. Mishra, Xue-Feng Cong, Qingde Zhuo, Kun An, M. Nishiura, Yi Luo, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2024

Hydroamination of alkenes with dinitrogen and titanium polyhydrides

T. Shima, Qingde Zhuo, Xiaoxi Zhou, Ping Wu, Ryota Owada, Gen Luo, Zhao-Min Hou

Nature

DOI

2023

Dinitrogen Activation and Addition to Unsaturated C-E (E = C, N, O, S) Bonds Mediated by Transition Metal Complexes.

Qingde Zhuo, Xiaoxi Zhou, T. Shima, Z. Hou

Angewandte Chemie

DOI

2023

Diastereo- and Enantioselective Hydrophosphination of Cyclopropenes under Lanthanocene Catalysis.

Xiao-Bin Lin, Kun An, Qingde Zhuo, M. Nishiura, Xuefeng Cong, Z. Hou

Angewandte Chemie

DOI

2023

Aza-Michael Addition of Dinitrogen to α,β-Unsaturated Carbonyl Compounds in a Dititanium Framework.

Qingde Zhuo, Jimin Yang, Xiaoxi Zhou, T. Shima, Yi Luo, Zhao-Min Hou

Journal of the American Chemical Society

DOI

2022

Dinitrogen Cleavage and Functionalization with Carbon Dioxide in a Dititanium Dihydride Framework.

Qingde Zhuo, Jimin Yang, Zhenbo Mo, Xiaoxi Zhou, T. Shima, Yi Luo, Z. Hou

Journal of the American Chemical Society

DOI

2022

Dinitrogen activation and transformation by multimetallic polyhydride complexes

T. Shima, Qingde Zhuo, Z. Hou

Coordination chemistry reviews

DOI

2021

铱杂碳龙配合物的合成及反应性

李金华，卓庆德，卓凯玥，陈大发，夏海平

《化学学报》

2021

Regio- and Diastereoselective [3 + 2] Annulation of Aliphatic Aldimines with Alkenes by Scandium-Catalyzed β-C(sp3)-H Activation.

Xuefeng Cong, Qingde Zhuo, Na Hao, Zhenbo Mo, Gu Zhan, M. Nishiura, Z. Hou

Angewandte Chemie

DOI

2021

Enantioselective C-H Alkenylation of Ferrocenes with Alkynes by Half-Sandwich Scandium Catalyst.

Sha Lou, Qingde Zhuo, M. Nishiura, Gen Luo, Z. Hou

Journal of the American Chemical Society

DOI

2021

Theoretical mechanistic insights into dinitrogen cleavage by a dititanium hydride complex bearing PNP-pincer ligands.

Jimin Yang, Qingde Zhuo, Zhenbo Mo, Z. Hou, Yi Luo

Dalton Transactions

DOI

2020

Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity

Fanping Huang, Xu Zheng, Xinlei Lin, Linting Ding, Qingde Zhuo, Ting-Bin Wen, Hong Zhang, Haiping Xia

Chemical Science

DOI

2019

Rhodapentalenes: Pincer Complexes with Internal Aromaticity

Qingde Zhuo, Hong Zhang, Linting Ding, Jianfeng Lin, Xiaoxi Zhou, Yuhui Hua, Jun Zhu, Haiping Xia

iScience

DOI

2019

Formal [2 + 2 + 2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex

Jianfeng Lin, Linting Ding, Qingde Zhuo, Hong Zhang, Haiping Xia

Organometallics

DOI

2019

Successive modification of polydentate complexes gives access to planar carbon- and nitrogen-based ligands

Xiaoxi Zhou, Xin Pang, Li-Ming Nie, Cong-Qing Zhu, Kai-Yue Zhuo, Qingde Zhuo, Zhi-Xin Chen, Gang Liu, Hong Zhang, Zhen-Yang Lin, Haiping Xia

Nature Communications

DOI

2018

A missing member of conjugated N-heterocycles: realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne.

Xiaoxi Zhou, Fanping Huang, Chun-Liang Tang, Qingde Zhuo, Zhi-Xin Chen, Hong Zhang, Haiping Xia

Chemical Communications

DOI

2018

Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative

Jin-Hua Li, Huijun Kang, Kai-Yue Zhuo, Qingde Zhuo, Hong Zhang, Yu-Mei Lin, Haiping Xia

Chinese journal of chemistry

DOI

2018

Constraint of a ruthenium-carbon triple bond to a five-membered ring

Qingde Zhuo, Hong Zhang, Yuhui Hua, Huijun Kang, Xiaoxi Zhou, Xinlei Lin, Zhi-Xin Chen, Jianfeng Lin, Kai-Yue Zhuo, Haiping Xia

Science Advances

DOI

2017

Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity.

Xiaoxi Zhou, Jing-Jing Wu, Yu-Lei Hao, Cong-Qing Zhu, Qingde Zhuo, Haiping Xia, Jun Zhu

Chemistry

DOI

2017

Multiyne chains chelating osmium via three metal-carbon σ bonds

Qingde Zhuo, Jianfeng Lin, Yuhui Hua, Xiaoxi Zhou, Yifan Shao, Shiyan Chen, Zhi-Xin Chen, Jun Zhu, Hong Zhang, Haiping Xia

Nature Communications

DOI

2016

Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes.

Qingde Zhuo, Zhiyong Chen, Yuhui Yang, Xiaoxi Zhou, Feifei Han, Jun Zhu, Hong Zhang, Haiping Xia

Dalton Transactions

DOI

2016

Synthesis of Fused Metallaaromatics via Intramolecular C–H Activation of Thiophenes

Qingde Zhuo, Xiaoxi Zhou, Huijun Kang, Zhiyong Chen, Yuhui Yang, Feifei Han, Hong Zhang, Haiping Xia

DOI

2015

Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation

Xiaoxi Zhou, Xiehua He, Jianfeng Lin, Qingde Zhuo, Zhi-Xin Chen, Hong Zhang, Jian-Bo Wang, Haiping Xia

DOI

2014

过渡金属杂小环的扩环反应研究进展

卓庆德，王铜道，周小茜，张弘

《有机化学》

2014

Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds

Qingde Zhuo, Tong-Dao Wang, Xiaoxi Zhou, Hong Zhang

DOI

精选作品

期刊论文

Cascade Coupling of Dinitrogen, Carbon Monoxide, Carbon Dioxide, and Alkynes in a Dititanium Framework.

Dinitrogen Functionalization with Allene, Isocyanide, and Carbon Monoxide in a Dititanium Framework.

Construction of Multiple M–C Bonds: Chelation with Conjugated Carbon Chains

A ruthenium carbolong skeleton with ten carbon atoms

Denitrogenative Carbon Skeleton Cleavage and Reorganization of Pyridines by a Trinuclear Titanium Polyhydride Complex.

Enantioselective [3+2] Annulation of Aldimines with Alkynes by Scandium-Catalyzed C-H Activation.

Regio- and Stereoselective Hydroalkynylation of Internal Alkynes with Terminal Alkynes by Half-Sandwich Rare-Earth Catalysts.

Dinitrogen Cleavage and Multicoupling with Isocyanides in a Dititanium Dihydride Framework.

Denitrogenative Ring-Contraction of Pyridines to a Cyclopentadienyl Skeleton at a Dititanium Hydride Framework.

Regio- and Diastereoselective Annulation of α,β-Unsaturated Aldimines with Alkenes via Allylic C(sp3)-H Activation by Rare-Earth Catalysts.

Divergent Synthesis of Multi-Substituted Aminotetralins via [4+2] Annulation of Aldimines with Alkenes by Rare-Earth-Catalyzed Benzylic C(sp3)-H Activation.

(Z)-Selective Isomerization of 1,1-Disubstituted Alkenes by Scandium-Catalyzed Allylic C-H Activation.

Hydroamination of alkenes with dinitrogen and titanium polyhydrides

Dinitrogen Activation and Addition to Unsaturated C-E (E = C, N, O, S) Bonds Mediated by Transition Metal Complexes.

Diastereo- and Enantioselective Hydrophosphination of Cyclopropenes under Lanthanocene Catalysis.

Aza-Michael Addition of Dinitrogen to α,β-Unsaturated Carbonyl Compounds in a Dititanium Framework.

Dinitrogen Cleavage and Functionalization with Carbon Dioxide in a Dititanium Dihydride Framework.

Dinitrogen activation and transformation by multimetallic polyhydride complexes

铱杂碳龙配合物的合成及反应性

Regio- and Diastereoselective [3 + 2] Annulation of Aliphatic Aldimines with Alkenes by Scandium-Catalyzed β-C(sp3)-H Activation.

Enantioselective C-H Alkenylation of Ferrocenes with Alkynes by Half-Sandwich Scandium Catalyst.

Theoretical mechanistic insights into dinitrogen cleavage by a dititanium hydride complex bearing PNP-pincer ligands.

Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity

Rhodapentalenes: Pincer Complexes with Internal Aromaticity

Formal [2 + 2 + 2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex

Successive modification of polydentate complexes gives access to planar carbon- and nitrogen-based ligands

A missing member of conjugated N-heterocycles: realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne.

Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative

Constraint of a ruthenium-carbon triple bond to a five-membered ring

Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity.

Multiyne chains chelating osmium via three metal-carbon σ bonds

Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes.

Synthesis of Fused Metallaaromatics via Intramolecular C–H Activation of Thiophenes

Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation

过渡金属杂小环的扩环反应研究进展

Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds

会议论文

新型四齿、五齿钳形配合物的合成与表征

噻吩C-H活化法构筑锇苯炔并噻吩和钌苯并噻吩

金促进炔烃亲电环化反应合成锇苯并噻吩

碘鎓化合物的分离与表征

噻吩并锇杂喹啉盐的合成与表征

锇杂戊搭炔与铜盐、金盐的反应

研究方向