郦鑫耀｜上海大学｜学者主页

2026

Nickel-catalyzed annulation of strained cyclic allene and benzodicarboxylic anhydride

Yi-Feng Guo, Zi-Jun Zhou, Lei Cui, Peng Xu, Xinyao Li, Jian Li

Organic Chemistry Frontiers

DOI

2026

DMSO‐Modulated Divergent Fluoroalcohol Addition to Alkenes via Cooperative Iron/Disulfide Photocatalysis

Huaixuan Guo, Shiqin Qiu, Bojing Deng, Fangzhuo Qin (24363900), Xinyao Li, Jian Li, Peng Xu

Angewandte Chemie

DOI

2026

B/Pd-Catalyzed Asymmetric Propargylic Substitution for Vicinal Quaternary/Tertiary Stereocenters

Zhihe Cen, Hua Liang, Guanzhen Zhao, Fan Wu, Xinyao Li, Xiaoyu Wu

Journal of the American Chemical Society

DOI

2026

Catalytic Asymmetric Dearomative Cyclizations of Indolyldimethanols via Umpolung Strategy

Ping Wu, Wen-Tao Zhang, Xian‐Yang Yu, Xinyao Li, Wei Wen Tan, Feng Jian Shi

JACS Au

DOI

2026

Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Iodocarboranes with Triarylarsanes and Triphenylstibanes

Xiaohai Wang, Meitian Fu, Xuran Pan, Jiaxin Xi, Zheng Wang, Xinyao Li, Shimeng Li

Journal of the American Chemical Society

DOI

2026

Visible-light-promoted nickel-catalyzed cross-coupling of B-iodocarboranes with styrenes

Xueyu Wang, Hangcheng Ni, Zhipeng Wang, Xinyao Li, Shimeng Li

Chemical Science

DOI

2026

Regioselective nitroarene reductive triflation via proton-shuttle-mediated [1,3]-rearrangement

Bin Lyu, Lei Zhu, Xinyao Li, Haoming Qin, Xiaomeng Shi, Xiaotian Qi, Song Song

Chinese Chemical Letters

DOI

2026

Catalytic endo-stereoselective [2+2] cycloaddition of norbornadienes with internal alkynes

Longji Dai, Gufeng Yin, Zekun Tuo, Zhichao Chang, Xinye Xia, Zhongjin Zuo, Yongchun Hu, Shuangshuang Li, Shugen Kuang, Yunfei Lai, Tzumei Wang, Chao Wang, Chong Qin, Xinyao Li, Wang Zhou

Nature Chemistry

DOI

2026

Iron-photocatalyzed decarboxylative allylation of aspartic and glutamic acid derivatives

Hongyao Li, Yang Li, Mengyang Dong, Xinyao Li

Organic & Biomolecular Chemistry

DOI

2025

Photocatalytic Radical Bis(trifluoromethyl)carbinolation of Alkenes and Heteroarenes.

Shi-Qin Qiu, Xiaoye Yu, Huai-Xuan Guo, Jian Li, Xinyao Li, Peng Xu

Angewandte Chemie

DOI

2025

Rhodium-Catalyzed Cycloaddition of Bicyclo[1.1.0]butanes with N,N’-Cyclic Azomethine Imines: En Route to Fused Diaza-3D Scaffolds

Tianlei Du, Qiu-Jie Qin, Jin Li, Yu-Ting Shen, Zixi Wang, K. Yin, Xinyao Li, Jian Li, Zi-Jun Zhou

Organic Chemistry Frontiers

DOI

2025

Photoredox/Nickel-Cocatalyzed Asymmetric C-O and C-S Couplings for Atroposelective Synthesis of N-Heterobiaryls.

Tian-Zhen Li, Cheng-Cheng Tian, Wei Chen, Zi-Yun Zou, Jia-Liang Yang, Fang-Xi Liu, Xinyao Li, Hong-Hao Zhang, Feng Shi

Angewandte Chemie

DOI

2025

Decarboxylative Alkylation of Difluoroenoxysilanes via Visible Light‐Excited EDA Complex

Hao Yang, Xinyao Li

Annalen der Pharmacie

DOI

2025

Visible-light-mediated C−S bond activation in cysteine derivatives with quinoxalinones for the synthesis of heteroaryl amino acids

Xinyao Li, Shuqi Ling, Jingjie Hai

Organic Chemistry Frontiers

DOI

2025

Selective Benzylic Cross-Dehydrogenative Arylation and α,β-Dehydrogenation Under Mild Conditions

Zhenyang Wan, Jiahao Gu, Yuhong Lu, Xian-Zhi Tian, Ziyue Zeng, Yichuan Yan, Xinyao Li, Dailin Zhuang, Ziyuan Li

Organic Chemistry Frontiers

DOI

2025

Direct regioselective C-3 halogenation of pyridines

Chao Li, Xinyao Li, Jiaxing Li, Zhixing Wang, Dunhuang Ouyang, Ning Jiao, Song Song

Nature Synthesis

DOI

2025

Asymmetric Access to Phosphinates via Nickel-Catalyzed Hydrophosphorylation of Alkynes

Bingbing Xu, Zhiyou Gao, Chang Liu, Jie Zhang, Jian Li, Xinyao Li, Tianjiao Hu

ACS Catalysis

DOI

2025

Visible-Light-Excited Lewis Acid Catalyzed Intermolecular [2σ + 3π] Photocycloadditions

Tianlei Du, Yunzhi Xie, Qiujie Qin, Kun Yin, Jian Li, Xinyao Li, Zijun Zhou

Organic Letters

DOI

2025

Green‐Light Photocatalytic Synthesis of Non‐Proteinogenic Isothiocyanate‐Decorated Amino Acids from Lysine Residues and Carbon Disulfide

Jingjie Hai, Hongyao Li, Yang Li, Xinyao Li

Advanced Synthesis & Catalysis

DOI

2025

Diastereo- and Enantioselective Allylation of α-Hydroxy Ketones Enabled by Palladium/Borinic Acid Dual Catalysis

Fan Wu, Kai Huang, Zhihe Cen, Changwen Yan, Yu‐He Kan, Xinyao Li, Xiaoyu Wu

ACS Catalysis

DOI

2025

Catalytic remodeling of complex alkenes to oxonitriles through C=C double bond deconstruction

Zengrui Cheng, Kaimeng Huang, Chen Wang, Lili Chen, Xinyao Li, Zhibin Hu, Xinyuan Shan, Pengfei Cao, Haofeng Sun, Wei Chen, Chenhao Li, Ziyao Zhang, Hui Tan, Xue Yin Jiang, Guikai Zhang, Zhongying Zhang, Min Lin, Liang Wang, Anmin Zheng, Changjiu Xia, Teng Wang, Song Song, Xingtian Shu, Ning Jiao

Science

DOI

2024

Orienting Group Directed Cascade Borylation for Efficient One-Shot Synthesis of 1,4-BN-Doped Polycyclic Aromatic Hydrocarbons as Narrowband Organic Emitters.

Lin Wu, Zhong-Yan Huang, Jing-Sheng Miao, Shuni Wang, Xinyao Li, Neng-Quan Li, Xiao-Song Cao, Chu-Luo Yang

Angewandte Chemie

DOI

2024

Chemoselective Construction of Polycyclic Heterocycles Containing a [6-6-5] or [7-6-5] Tricyclic Core Skeleton from a 2-Isocyanophenyl Propargylic Ester.

Youwen Fei, Zi-Jun Zhou, Zihan Ni, Xin Peng, Lei Cui, Zi-Jun Zhou, Xinyao Li, Chun-Ju Li, Xue-Shun Jia, Jian Li

Angewandte Chemie

DOI

2024

Three-component Formal Metathesis via Remote Activating Strategy Enabled (RASE) Domino Activation of Two C(sp3)-O Bonds in Alkyl Ethers

Dailin Zhuang, Le Cheng, Yichuan Yan, Yu-Ting Tang, Zhenyang Wan, Jiahao Gu, Yuhong Lu, Xinyao Li, Ziyuan Li

Organic Chemistry Frontiers

DOI

2024

Synthesis of β-Carbonyl α-Iminoamides by Double Insertion of Isocyanides into Aldehydes

Di Lu, Shaohang Lu, Chang‐Hua Ding, Xinyao Li, Bin Xu

Organic Letters

DOI

2024

Theoretical Insights into the Regiodivergence in Ni-Catalyzed [2+2+2] Cycloaddition of Unsymmetric Diynes and CO2

Kun Zhang, Qiwen Huang, Cun Bo Yang, Xinyao Li

Inorganics

DOI

2024

Copper nitrate-enabled ring expansion reaction of cyclopropanes: a direct approach to 3-cyano-isoxazoline N -oxides

Yong Deng, Zhenkun Yang, Yanze Li, Xinyao Li, Bin Xu

Organic Chemistry Frontiers

DOI

2024

Theoretical insights into the enantiodivergence induced by chiral phosphoric acid catalysis with a Lewis acid for the synthesis of N–N axially chiral atropisomers

Yanze Li, Xinyao Li

Organic & Biomolecular Chemistry

DOI

2023

Atroposelective synthesis of N–N axially chiral pyrrolyl(aza)-quinolinone by de novo ring formation

Qiwen Huang, Yanze Li, Cun Bo Yang, Wendan Wu, Jingjie Hai, Xinyao Li

Organic Chemistry Frontiers

DOI

2023

Lewis Acid Catalyzed [4+1] Cycloaddition of o-Quinone Methides and Isocyanides: Mild and Efficient Synthesis of 3-Aryl-2-aminobenzofurans

Xinyao Li, Cun Bo Yang, Yanze Li, Qiwen Huang

Synlett

DOI

2021

Synthesis of β-Phosphinolactams from Phosphenes and Imines

Xingyang Fu, Xinyao Li, Jiaxi Xu

Organic Letters

DOI

2020

Enantioselective, Visible Light Mediated Aza Paternò–Büchi Reactions of Quinoxalinones

Xinyao Li, John Grosskopf, Christian Jandl, Thorsten Bach

Angewandte Chemie

DOI

2019

氧气氧化铜催化的苯胺邻位叠氮化反应

林凤闺蓉，梁宇杰，郦鑫耀，宋颂，焦宁

《化学学报》

2019

实现苯胺类与炔烃的选择性一氧化氮片段化或整体性嵌入

潘军，郦鑫耀，Fengguirong Lin，Jianzhong Liu，焦宁

《科学新闻》

2009

二级卤代烷亲核取代反应立体选择性差别的解释

郦鑫耀，许家喜

《大学化学》

精选作品

期刊论文

Nickel-catalyzed annulation of strained cyclic allene and benzodicarboxylic anhydride

DMSO‐Modulated Divergent Fluoroalcohol Addition to Alkenes via Cooperative Iron/Disulfide Photocatalysis

B/Pd-Catalyzed Asymmetric Propargylic Substitution for Vicinal Quaternary/Tertiary Stereocenters

Catalytic Asymmetric Dearomative Cyclizations of Indolyldimethanols via Umpolung Strategy

Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Iodocarboranes with Triarylarsanes and Triphenylstibanes

Visible-light-promoted nickel-catalyzed cross-coupling of B-iodocarboranes with styrenes

Regioselective nitroarene reductive triflation via proton-shuttle-mediated [1,3]-rearrangement

Catalytic endo-stereoselective [2+2] cycloaddition of norbornadienes with internal alkynes

Iron-photocatalyzed decarboxylative allylation of aspartic and glutamic acid derivatives

Photocatalytic Radical Bis(trifluoromethyl)carbinolation of Alkenes and Heteroarenes.

Rhodium-Catalyzed Cycloaddition of Bicyclo[1.1.0]butanes with N,N’-Cyclic Azomethine Imines: En Route to Fused Diaza-3D Scaffolds

Photoredox/Nickel-Cocatalyzed Asymmetric C-O and C-S Couplings for Atroposelective Synthesis of N-Heterobiaryls.

Decarboxylative Alkylation of Difluoroenoxysilanes via Visible Light‐Excited EDA Complex

Visible-light-mediated C−S bond activation in cysteine derivatives with quinoxalinones for the synthesis of heteroaryl amino acids

Selective Benzylic Cross-Dehydrogenative Arylation and α,β-Dehydrogenation Under Mild Conditions

Direct regioselective C-3 halogenation of pyridines

Asymmetric Access to Phosphinates via Nickel-Catalyzed Hydrophosphorylation of Alkynes

Visible-Light-Excited Lewis Acid Catalyzed Intermolecular [2σ + 3π] Photocycloadditions

Green‐Light Photocatalytic Synthesis of Non‐Proteinogenic Isothiocyanate‐Decorated Amino Acids from Lysine Residues and Carbon Disulfide

Diastereo- and Enantioselective Allylation of α-Hydroxy Ketones Enabled by Palladium/Borinic Acid Dual Catalysis

Catalytic remodeling of complex alkenes to oxonitriles through C=C double bond deconstruction

Orienting Group Directed Cascade Borylation for Efficient One-Shot Synthesis of 1,4-BN-Doped Polycyclic Aromatic Hydrocarbons as Narrowband Organic Emitters.

Chemoselective Construction of Polycyclic Heterocycles Containing a [6-6-5] or [7-6-5] Tricyclic Core Skeleton from a 2-Isocyanophenyl Propargylic Ester.

Three-component Formal Metathesis via Remote Activating Strategy Enabled (RASE) Domino Activation of Two C(sp3)-O Bonds in Alkyl Ethers

Synthesis of β-Carbonyl α-Iminoamides by Double Insertion of Isocyanides into Aldehydes

Theoretical Insights into the Regiodivergence in Ni-Catalyzed [2+2+2] Cycloaddition of Unsymmetric Diynes and CO2

Copper nitrate-enabled ring expansion reaction of cyclopropanes: a direct approach to 3-cyano-isoxazoline N -oxides

Theoretical insights into the enantiodivergence induced by chiral phosphoric acid catalysis with a Lewis acid for the synthesis of N–N axially chiral atropisomers

Atroposelective synthesis of N–N axially chiral pyrrolyl(aza)-quinolinone by de novo ring formation

Lewis Acid Catalyzed [4+1] Cycloaddition of o-Quinone Methides and Isocyanides: Mild and Efficient Synthesis of 3-Aryl-2-aminobenzofurans

Synthesis of β-Phosphinolactams from Phosphenes and Imines

Enantioselective, Visible Light Mediated Aza Paternò–Büchi Reactions of Quinoxalinones

氧气氧化铜催化的苯胺邻位叠氮化反应

实现苯胺类与炔烃的选择性一氧化氮片段化或整体性嵌入

二级卤代烷亲核取代反应立体选择性差别的解释

会议论文

氧和氮杂原子[1,3]σ迁移反应研究

预印本

Alkyne Cleavage and Selective Use of the Resulting Fragment as C1 Synthon

研究方向